Gas-Phase Fluorophore Dataset Notes¶
| Fluorophore | Class | Charge | \(\lambda_{max}^{abs}\) | \(\lambda_{max}^{em}\) | \(\Delta E_{0-0}\) | DOI | Other notes |
|---|---|---|---|---|---|---|---|
| 8-methoxy-BODIIPY | BODIPY | 0 | 2.81 | 2.59 | 2.6 | 10.26434/chemrxiv.11639931.v1 | |
| 441 | 479 | 461 | |||||
| Fluorescein | xanthene | -1 | 2.36 | 2.10 | 2.27-2.28 | 10.1039/D0CP00453G | Deprotonated at the xanthene 0-0 is extracted from figure |
| Rhodamine 575 | xanthene | +1 | 2.50 | 2.45 | 2.47 | 10.1007/s13361-010-0017-4 | Protonated amine, pronated carboxylic acid 0-0 is extracted from figure |
| Azulene (\(s_2\)) | azulene | 0 | 3.565 fluor | 10.1016/0301-0104(83)85076-9 | |||
| Azulene (\(s_1\)) | 4.23 fluor | ||||||
| Azulene (\(s_2\)) | 3.565 abs | 10.1039/c5cp01826a | From PES study \(s_2\) is not \(\lambda_{max}\) |
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| Azulene (\(s_1\)) | 1.771 abs | ||||||
| Azulene (\(s_2\)) Deconvoluted |
3.56 | 3.31 | 3.43 | \(S_1\) could not be identified in these plots 0-0 taken form average of abs and em wavelengths |
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| Coumarin 153 | coumarin | 0 | 417 | 368 | 3.152 | 10.1039/A902491C | \(\lambda_{max}\) was extracted from figure 1 |
Azulene Deconvolution¶
These were manually extracted from a paper by hand, plotting over the screenshots in excel.
Blue peak on the right (356nm) is \(s_0\to s_2\)
Greyish brown peak on the left (300nm) is \(s_0\to s_3\)
I’m not sure what the grey and pinkish peaks are.
Tallest peak is \(s_2\to s_0\)
